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Usage stats on Urahara said that souls whose chain of fate have been severed take 72 hoursbefore turning into hollows but Orihime's brother has been dead for 3 years before he became a hollow so how is this possible

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an Entity in Data Space: dbkwik.org

You missed a key detail: Urahara was talking about what happened in the Shattered Shaft only. It is established throughout the rest of the series that it takes months for a Plus to become a Hollow under normal circumstances.

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